Credit: University of Montreal
The main advantage of AzoBiPy is
that it can exchange two electrons rather than just one. This means each
molecule can store twice as much energy as a single-electron molecule, doubling
the system's capacity.
"But the biggest challenge
with these organic molecules is stability," said Lebel. "It must be
possible for the charge-discharge cycle to run for a long time without the
molecule breaking down."
This is where AzoBiPy shines. The
team tested a flow battery based on this molecule by operating it for 70
consecutive days, completing 192 full charge-discharge cycles. At the end of
the trial, the molecule retained nearly 99% of its initial capacity—a performance
the researchers describe as exceptional for an organic molecule.
From laboratory to application
In a festive demonstration at the
Department of Chemistry's holiday party in December 2024, the prototype flow
battery powered a set of Christmas tree lights for eight hours with tanks
containing only about two tablespoons of aqueous solution each.
This demonstration also highlighted
another major advantage of the system: It is water-based and therefore non-flammable, unlike lithium-ion
batteries, which present a fire risk. "This feature is especially
important for large-scale, stationary energy storage facilities," said
Rochefort.
Flow batteries powered by molecules
such as AzoBiPy could be used to store electricity generated by solar or wind
farms. Long-term storage of intermittently generated electricity would make it
possible to use it at a later date to meet peak demand.
There could also be residential
applications. "It may be possible to develop smaller-scale systems with
greener, safer batteries for home use," Lebel suggested.
The research team is drafting a patent application and is already working on the next stages. "We're preparing a scientific article that describes a family of molecules with properties similar to AzoBiPy," said Lebel. "An entire class of compounds with potential for renewable energy storage is opening up to exploration. We expect this technology to be in wider use within 10 to 15 years."

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