Credit: Chemistry of Materials (2026). DOI: 10.1021/acs.chemmater.5c02442
Conventional
lithium-ion batteries contain problematic substances such as nickel and cobalt,
and the solvents used to coat the electrode materials are also toxic. Materials
scientists at Saarland University are therefore working to develop
environmentally friendly alternatives. By introducing finely dispersed iron
oxide into tiny, highly porous, hollow carbon spheres developed by Professor
Michael Elsaesser at the University of Salzburg, the Saarbrücken team has
achieved some very promising results: higher storage capacities using materials
that are both readily available and environmentally far less problematic. These
results have now been published in Chemistry
of Materials.
Anyone who has ever been to Salzburg in
Austria will be acquainted with Mozartkugeln—the famous chocolate-coated balls
of marzipan and nougat. And Mozartkugeln are a simple way of imagining the
hollow carbon spheres that were developed by researchers at Salzburg University
and are now being used at Saarland University to advance lithium-ion battery
technology. Known as carbon spherogels,
these novel materials are nanometer-sized units around 250 nm in diameter that
offer a large surface area and high electrochemical capacity.
"The challenge for us is to use
chemical synthesis to fill the cavity inside these spheres with suitable metal
oxides," explains materials scientist Stefanie Arnold. After a set of
initial experiments with titanium dioxide, whose ability to store and release
lithium ions was relatively low, the team turned their attention to iron oxide,
which most of us commonly refer to as rust.
"Iron has a number of advantages:
it is abundant worldwide, it offers—in theory at least—a high storage capacity,
and it's easy to recycle," says Arnold, a postdoctoral researcher at
Saarland University working with Professor Volker Presser, Professor of Energy
Materials. Using a scalable synthesis methodology based on iron lactate,
the Salzburg team was able to integrate different quantities of iron into the
carbon framework of the hollow spheres, producing robust porous networks with
evenly distributed iron nanoparticles.
"What
was particularly interesting was that the storage capacity (i.e., the amount of
electric charge that can be reversibly stored and released per gram of active
electrode material) continued to increase while the battery was in use. The
longer the battery was used, the better it performed. This is because the
elemental metallic iron in the nanoparticles first has to react with oxygen to
form iron oxide.
"This
process of electrochemical activation of the iron
embedded in the carbon spherogel matrix is not immediate but happens
progressively. It takes around 300 charge-discharge cycles until all the
cavities in the carbon spheres are filled with iron oxide and the maximum
storage capacity is reached," explains Arnold.
Materials scientist Stefanie Arnold is
searching for environmentally friendly alternatives for energy storage. Credit:
Oliver Dietze, Universität des Saarlandes
'Rust-based batteries' are still a work in progress
However, further research is still
needed before this mechanism can be used on an industrial scale. The activation
process needs to be faster so that batteries can reach their maximum storage
capacity sooner. In addition, the iron oxide-filled carbon spherogels are
currently used as the battery anode; a suitable cathode still needs to be
developed to obtain a complete cell.
"We are confident that our
approach will facilitate the development of environmentally friendly buffer
storage systems for renewable energy," says Prof. Presser, who also heads
the Research Department Energy Materials at the INM—Leibniz Institute for New
Materials in Saarbrücken. The new material will also be tested for sodium-ion
batteries, which Chinese automotive manufacturers are already deploying.
"These materials form a
versatile technology platform that allows a wide variety of other substances to
be integrated in situ into the spherogels in a single synthesis step, opening
up opportunities for a wide range of technological applications," adds
Elsässer.
Developing new recycling methods and a climate-friendly energy supply
As part of the EnFoSaar project,
Arnold is also investigating how lithium can be recovered from batteries and
how future batteries should be designed so that they can be dismantled on an
industrial scale. "We need efficient recycling
methods and
closed-loop material systems to minimize resource consumption and reduce waste
in the battery supply chain," says Arnold.
The EnFoSaar project aims to
develop innovative approaches for a climate-friendly energy supply and to drive
the transformation of Saarland's energy industry and the associated research
landscape by developing innovative, scientifically sound, and practically
implementable methodologies.
Provided by Saarland
University
by Friederike Meyer zu Tittingdorf, Saarland University
edited
by Lisa
Lock, reviewed by Robert Egan
Source: Batteries
from rust? Carbon spheres filled with iron oxide deliver high storage capacity