Nucleation-promoting and growth-limiting
molten-salt synthesis method (NM synthesis). Credit: Nature Communications (2025). DOI: 10.1038/s41467-025-60946-4
A team of McGill University
researchers, working with colleagues in the United States and South
Korea, has developed a new way to make high-performance lithium-ion
battery materials that could help phase out expensive and/or
difficult-to-source metals like nickel and cobalt.
The team's breakthrough lies in
creating a better method of producing "disordered rock-salt" (DRX)
cathode particles, an alternative battery material. Until now, manufacturers
struggled to control the size and quality of DRX particles, which made them
unstable and hard to use in manufacturing settings. The researchers addressed
that problem by developing a method to produce uniformly sized, highly
crystalline particles with no grinding or post-processing required.
"Our method enables mass
production of DRX cathodes with consistent quality, which is essential for
their adoption in electric vehicles and renewable energy storage," said Jinhyuk Lee, the paper's
corresponding author and an Assistant Professor in the Department of Mining and
Materials Engineering.
The researchers say the findings,
published in Nature Communications, offer a promising path toward
more sustainable and cost-effective lithium-ion batteries, a critical component in the global shift to electrified transportation
and the use of renewable power.
A materials breakthrough
The researchers devised a
two-step molten salt process to synthesize the DRX particles. Molten salt enables better
control over particle formation, improving quality and efficiency. First, the
researchers promoted nucleation (the formation of small, uniform crystals) of
the particles, and then limited their growth. This allowed them to produce
battery-ready particles that are smaller than 200 nanometers, a size considered
important for unlocking these materials' performance in lithium-ion batteries.
"We developed the first method
to directly synthesize highly crystalline, uniformly dispersed DRX single
particles without the need for post-synthesis grinding," said Lee.
"This morphological control enhances both battery performance and the
consistency of large-scale DRX cathode production."
When tested in battery cells, the
new materials maintained 85 percent of their capacity after 100
charge-discharge cycles. That's more than double the performance of DRX
particles produced using older methods.
The necessity of annealing and
Li-reinsertion after washing of NM-LMTO in decoupling the crystallinity and the
particle size. Credit: Nature Communications (2025). DOI: 10.1038/s41467-025-60946-4
From lab to industry
The research was carried out by a
McGill team in collaboration with scientists at Stanford University's SLAC
National Accelerator Laboratory and the Korea Advanced Institute of Science and
Technology (KAIST). It was supported in part by Wildcat Discovery Technologies,
a U.S.-based battery company interested in scaling DRX technologies for
commercial use.
The team's method could also make
the process more scalable and energy efficient, addressing a key hurdle to the
widespread adoption of DRX cathodes. Given the global demand for batteries,
that could have a major ripple effect.
"Acceptance of our work
highlights both the fundamental insight and industrial potential of the
method," said Hoda Ahmed, the lead author of the paper and a Ph.D. student
in McGill's Department of Materials Engineering. "It shifts the field
toward scalable manufacturing."
With this synthesis strategy, the
researchers say the door is now open to next-generation lithium-ion batteries
that are more sustainable, more affordable, and easier to produce at scale.
"Nucleation-promoting and growth-limiting synthesis of disordered rock-salt Li-ion cathode materials," by Hoda Ahmed, Moohyun Woo, Raynald Gauvin, George Demopoulos, Jinhyuk Lee, and colleagues, was published in Nature Communications.
Source: New method replaces nickel and cobalt in battery for cleaner, cheaper lithium-ion batteries
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