Scientists create gold hydride by combining gold and hydrogen under extreme conditions - Chemistry Materials Science

Illustration of intense pulses from an X-ray free-electron laser (left) heating compressed samples of hydrocarbons to extreme conditions, resulting in the reaction of gold and hydrogen to form gold hydride (center). The gold atoms, shown in gold, are fixed in a hexagonal crystal lattice through which the hydrogen, shown in white, diffuses freely in a “superionic” state. Credit: Greg Stewart/SLAC National Accelerator Laboratory

Serendipitously and for the first time, an international research team led by scientists at the U.S. Department of Energy's SLAC National Accelerator Laboratory formed solid binary gold hydride, a compound made exclusively of gold and hydrogen atoms.

The researchers were studying how long it takes hydrocarbons, compounds made of carbon and hydrogen, to form diamonds under extremely high pressure and heat.

In their experiments at the European XFEL (X-ray Free-Electron Laser) in Germany, the team studied the effect of those extreme conditions in hydrocarbon samples with an embedded gold foil, which was meant to absorb the X-rays and heat the weakly absorbing hydrocarbons. To their surprise, they not only saw the formation of diamonds, but also discovered the formation of gold hydride.

"It was unexpected because gold is typically chemically very boring and unreactive—that's why we use it as an X-ray absorber in these experiments," said Mungo Frost, staff scientist at SLAC who led the study.

"These results suggest there's potentially a lot of new chemistry to be discovered at extreme conditions where the effects of temperature and pressure start competing with conventional chemistry, and you can form these exotic compounds."

The results, published in Angewandte Chemie International Edition, provide a glimpse of how the rules of chemistry change under extreme conditions like those found inside certain planets or hydrogen-fusing stars.

Studying dense hydrogen

In their experiment, the researchers first squeezed their hydrocarbon samples to pressures greater than those within Earth's mantle using a diamond anvil cell. Then, they heated the samples to over 3,500 degrees Fahrenheit by hitting them repeatedly with X-ray pulses from the European XFEL.

The team recorded and analyzed how the X-rays scattered off the samples, which allowed them to resolve the structural transformations within.

As expected, the recorded scattering patterns showed that the carbon atoms had formed a diamond structure. But the team also saw unexpected signals that were due to hydrogen atoms reacting with the gold foil to form gold hydride.

Under the extreme conditions created in the study, the researchers found hydrogen to be in a dense, "superionic" state, where the hydrogen atoms flowed freely through the gold's rigid atomic lattice, increasing the conductivity of the gold hydride.

Hydrogen, which is the lightest element in the periodic table, is tricky to study with X-rays because it scatters X-rays only weakly. Here, however, the superionic hydrogen interacted with the much heavier gold atoms, and the team was able to observe hydrogen's impact on how the gold lattice scattered X-rays.

"We can use the gold lattice as a witness for what the hydrogen is doing," Mungo said.

The gold hydride offers a way to study dense atomic hydrogen under conditions that might also apply to other situations that are experimentally not directly accessible. For example, dense hydrogen makes up the interiors of certain planets, so studying it in the lab could teach us more about those foreign worlds.

It could also provide new insights into nuclear fusion processes inside stars like our sun and help develop technology to harness fusion energy here on Earth.

Exploring new chemistry

In addition to paving the way for studies of dense hydrogen, the research also offers an avenue for exploring new chemistry. Gold, which is commonly regarded as an unreactive metal, was found to form a stable hydride at extremely high pressure and temperature.

In fact, it appears to be only stable at those extreme conditions, as when it cools down, the gold and hydrogen separate. The simulations also showed that more hydrogen could fit in the gold lattice at higher pressure.

The simulation framework could also be extended beyond gold hydride.

"It's important that we can experimentally produce and model these states under these extreme conditions," said Siegfried Glenzer, High Energy Density Division director and professor of photon science at SLAC and the study's principal investigator.

"These simulation tools could be applied to model other exotic material properties in extreme conditions." 

by SLAC National Accelerator Laboratory               Editors' notes

edited by Sadie Harley, reviewed by Andrew Zinin 

Source: Scientists create gold hydride by combining gold and hydrogen under extreme conditions