Sample pieces of glaze-coated tile (b) tea solutions before and after mixing with glazes (top) and degraded tea solutions with and without existence of glazes (bottom). Credit: Takashi Shirai from NITech, Japan
Introduced
as a medicinal drink around 2700 B.C., tea has grown to be the one of the most
popular beverages worldwide. One of the key reasons for its popularity is its
rich content of flavonoids and polyphenols, which contribute to the antioxidant
property, flavor, and aroma of tea, offering various potential health benefits.
These compounds are extracted from tea leaves during brewing and can be
influenced by several factors, such as water temperature, brewing time, and the
materials used in tea preparation vessels.
Recently, researchers from Nagoya
Institute of Technology (NITech) in Japan have revealed, for the first time,
that the choice of glazing on ceramic tea sets used to prepare tea plays a key
role in the retention of catechin flavonoids.
In their study published online in the journal Scientific Reports, Associate Professor Takashi Shirai, along with Dr.
Yunzi Xin, Mr. Sota Shido, and Dr. Kunihiko Kato from the Advanced Ceramics
Research Center at NITech, examined the impact of four different typical
Japanese commercial glazes—Oribe, Namako, Irabo, and Toumei—on the content of
catechins, the most abundant flavonoid found in green tea.
While glaze coatings primarily consist of feldspar minerals, such as silicon, aluminum, sodium, and calcium oxides, they also contain distinct metal oxide species that impart a unique appearance and texture to the ceramic vessel. Oribe glaze predominantly contains copper (Cu) oxides and imparts a vibrant green color, while Namako glaze contains cobalt (Co) oxides for a dark blue appearance. Irabo glaze contains iron (Fe) oxides that impart orange tones, while Toumei glaze has a high titanium (Ti) content, providing a transparent finish.
Glazes on
tea sets significantly reduce the amount of catechins in tea by oxidizing them,
altering the flavor, aroma, and health benefits of tea. Credit: Dr. Takashi
Shirai from NITech, Japan
To
examine the effect of the glaze on tea catechins, the researchers brewed a
green tea solution using ion-exchanged water at 80°C for three minutes. The tea
leaves were separated, and the supernatant (liquid lying above solid residue)
was mixed with glaze powders coated on ceramic tiles. The glaze–tea mixture was
then allowed to react for six hours, followed by the removal of the glaze
powder through centrifugation and filtration.
The researchers observed that the
pristine tea solution had a clear bright yellow color, but after six hours of
degradation, it turned into a yellowish-brown color. In contrast, the tea
solutions degraded by different glazes exhibited darker black or brown colors.
In other words, the extent of color change depended significantly on the type
of glaze.
Additionally, the researchers also
observed a selective reduction in the amount of altered catechins in tea. The
tea solutions mixed with Oribe, Namako, and Irabo glazes showed significantly
lower concentrations of epicatechin, epicatechin gallate, epigallocatechin, and
epigallocatechin gallate, while the Toumei glaze selectively degraded
epigallocatechin gallate. The reduction in catechin concentration and the
resulting color change can be attributed to the oxidation process of catechins,
which forms brownish thearubigins and reddish-orange theaflavin and its oxide
pigments.
"During the degradation process,
Cu-, Co-, Fe-, and Ti-oxides in glaze powders can act as a Lewis acid catalyst
and promote the oxidation of catechin molecules to ortho-quinones, followed by
further reaction to form thearubigins and/or theaflavin and its oxides. Another
oxidation route is through the polymerization of intermediate free radical
catechins," explains Dr. Shirai. "And it is very interesting that
thearubigins and theaflavins are the main components of fermented tea like
black tea. In other words, green tea brewed by specific ceramic tea sets can be
turned into black tea."
In summary, this study highlights that the choice of glaze materials used in ceramic tea sets can significantly affect the concentration of beneficial compounds such as catechins in tea. "The specific function of glazes on the degradation of catechins not only provides principal information for the design and development of functional materials but can also impact daily tea drinking and long-term human health-related issues," concludes Dr. Shirai.
by Nagoya
Institute of Technology
Source: Ceramic tea set glazing affects health benefits of tea, finds new study (phys.org)
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