NASA's Perseverance rover was traveling in the channel
of an ancient river, Neretva Vallis, when it captured this view of an area of
scientific interest nicknamed "Bright Angel" – the light-toned area
in the distance at right. The area features light-toned rocky outcrops that may
represent either ancient sediment that later filled the channel or possibly
much older rock that was subsequently exposed by river erosion.
NASA/JPL-Caltech
A new NASA study reveals a surprising
way planetary cores may have formed—one that could reshape how scientists
understand the early evolution of rocky planets like Mars.
Conducted by a team of early-career
scientists and long-time researchers across the Astromaterials Research and Exploration Science (ARES) Division at NASA’s Johnson Space Center in Houston, the study offers the first direct experimental and
geochemical evidence that molten sulfide, rather than metal, could percolate
through solid rock and form a core—even before a planet’s silicate mantle
begins to melt.
For decades, scientists believed that
forming a core required large-scale melting of a planetary body, followed by
heavy metallic elements sinking to the center. This study introduces a new
scenario—especially relevant for planets forming farther from the Sun, where
sulfur and oxygen are more abundant than iron. In these volatile-rich
environments, sulfur behaves like road salt on an icy street—it lowers the
melting point by reacting with metallic iron to form iron-sulfide so that it
may migrate and combine into a core. Until now, scientists didn’t know if
sulfide could travel through solid rock under realistic planet formation
conditions.
“Working on this project pushed us to be creative. It was exciting to see
both data streams converge on the same story.
Dr. Jake Setera
ARES Scientist with Amentum
The study results gave researchers a way
to directly observe this process using high-resolution 3D imagery—confirming
long-standing models about how core formation can occur through percolation, in
which dense liquid sulfide travels through microscopic cracks in solid rock.
“We could actually see in full 3D
renderings how the sulfide melts were moving through the experimental sample,
percolating in cracks between other minerals,” said Dr. Sam Crossley of the
University of Arizona in Tucson, who led the project while a postdoctoral
fellow with NASA Johnson’s ARES Division. “It confirmed our hypothesis—that in
a planetary setting, these dense melts would migrate to the center of a body
and form a core, even before the surrounding rock began to melt.”
Recreating planetary formation conditions in the lab required not only experimental precision but also close collaboration among early-career scientists across ARES to develop new ways of observing and analyzing the results. The high-temperature experiments were first conducted in the experimental petrology lab, after which the resulting samples—or “run products”—were brought to NASA Johnson’s X-ray computed tomography (XCT) lab for imaging.
A molten sulfide network (colored gold) percolates
between silicate mineral grains in this cut-out of an XCT rendering—rendered
are unmelted silicates in gray and sulfides in white.
Credit: Crossley et al. 2025, Nature Communications
X-ray scientist and study co-author Dr. Scott Eckley of Amentum at NASA
Johnson used XCT to produce high-resolution 3D renderings—revealing melt
pockets and flow pathways within the samples in microscopic detail. These
visualizations offered insight into the physical behavior of materials during
early core formation without destroying the sample.
The 3D XCT visualizations initially
confirmed that sulfide melts could percolate through solid rock under
experimental conditions, but that alone could not confirm whether percolative
core formation occurred over 4.5 billion years ago. For that, researchers
turned to meteorites.
“We took the next step and searched
for forensic chemical evidence of sulfide percolation in meteorites,” Crossley
said. “By partially melting synthetic sulfides infused with trace
platinum-group metals, we were able to reproduce the same unusual chemical
patterns found in oxygen-rich meteorites—providing strong evidence that sulfide
percolation occurred under those conditions in the early solar system.”
To understand the distribution of
trace elements, study co-author Dr. Jake Setera, also of Amentum, developed a
novel laser ablation technique to accurately measure platinum-group metals,
which concentrate in sulfides and metals.
“Working on this project pushed us
to be creative,” Setera said. “To confirm what the 3D visualizations were
showing us, we needed to develop an appropriate laser ablation method that
could trace the platinum group-elements in these complex experimental samples.
It was exciting to see both data streams converge on the same story.”
When paired with Setera’s geochemical analysis, the data provided powerful, independent lines of evidence that molten sulfide had migrated and coalesced within a solid planetary interior. This dual confirmation marked the first direct demonstration of the process in a laboratory setting.
Dr. Sam Crossley welds shut the glass tube of the
experimental assembly. To prevent reaction with the atmosphere and precisely
control oxygen and sulfur content, experiments needed to be sealed in a closed
system under vacuum.
Credit: Amentum/Dr. Brendan Anzures
The study offers a new lens through
which to interpret planetary geochemistry. Mars in particular shows signs of
early core formation—but the timeline has puzzled scientists for years. The new
results suggest that Mars’ core may have formed at an earlier stage, thanks to
its sulfur-rich composition—potentially without requiring the full-scale
melting that Earth experienced. This could help explain longstanding puzzles in
Mars’ geochemical timeline and early differentiation.
The results also raise new
questions about how scientists date core formation events using radiogenic
isotopes, such as hafnium and tungsten. If sulfur and oxygen are more abundant
during a planet’s formation, certain elements may behave differently than
expected—remaining in the mantle instead of the core and affecting the
geochemical “clocks” used to estimate planetary timelines.
This research advances our
understanding of how planetary interiors can form under different chemical
conditions—offering new possibilities for interpreting the evolution of rocky
bodies like Mars. By combining experimental petrology, geochemical analysis,
and 3D imaging, the team demonstrated how collaborative, multi-method
approaches can uncover processes that were once only theoretical.
Crossley led the research during
his time as a McKay Postdoctoral Fellow—a program that recognizes outstanding
early-career scientists within five years of earning their doctorate. Jointly
offered by NASA’s ARES Division and the Lunar and Planetary Institute in
Houston, the fellowship supports innovative research in astromaterials science,
including the origin and evolution of planetary bodies across the solar system.
As NASA prepares for future
missions to the Moon, Mars, and beyond, understanding how planetary interiors
form is more important than ever. Studies like this one help scientists
interpret remote data from spacecraft, analyze returned samples, and build better
models of how our solar system came to be.
For more information on NASA’s ARES
division, visit: https://ares.jsc.nasa.gov/
Victoria Segovia
NASA’s Johnson Space Center
Source: Percolating Clues: NASA Models New Way to Build Planetary Cores - NASA Science
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